Chemists from the Institute of Inorganic and Analytical Chemistry at the University of Freiburg (Germany; uni-freiburg.de) have synthesized a cationic, low-valence aluminum complex salt. “So far, there has been only one example of a cationic, low-valent aluminum compound, but it…
Zero-spin Silicon Natural silicon consists of three isotopes: 28Si (92.2%) and 30Si (3.1%) — each with zero electron spin state — and 29Si (4.7%) with a spin state of one half. The presence of 29Si in concentrations above 500 parts…
A new class of adhesives being developed by the startup gluECO Adhesives LLC (Ashburnham, Mass.; www.glueco-adhesives.com) is based on corn proteins and has a host of environmentally friendly properties, such as biodegradability and the ability to be easily removed in…
Biomethane Last month, NextChem, a subsidiary of Maire Tecnimont S.p.A. (Rome, Italy; www.mairetecnimont.com) was awarded a contract by ENGIE subsidiary Storengy (Bois-Colombes Cedex, France; www.storengy.com) to perform an advanced basic-engineering study for a plant that will produce second-generation biomethane from…
Circular dichroism (CD) is the established method for distinguishing between enantiomers — the optical isomers of molecules that are mirror images of each other. In this approach, circularly polarized light is passed through the sample and is absorbed differently by…
In an advancement toward circularity for commodity plastics, researchers at the Oak Ridge National Laboratory (ORNL; Oak Ridge, Tenn.; www.ornl.gov) have developed a method for upcycling the commodity thermoplastic acrylonitrile butadiene styrene (ABS) into an ABS-vitrimer material that can be…
An interdisciplinary team of biologists, chemists and engineers from the University of Portsmouth (U.K.; www.port.ac.uk) have become the first to successfully grow a limpet-inspired biomaterial with extreme strength. The common limpet (Patella vulgata) is a small, snail-like mollusk with a…
Cyclopropane-functionalized hydrocarbons can be excellent fuels because of their high energy densities, but organic synthesis of such fuels is difficult. In work recently published in the journal Joule, a research team led by Jay Keasling at the Joint Bioenergy Institute…
New hardware combined with monitoring technologies can help optimize combustion now and in the carbon-conscious future Combustion has long been a delicate balancing act. Chemical processors want their combustion systems to be fuel efficient and available for use, while at…
Transparent polymer film started with an accident . . . and spurred a packaging revolution One night in Paris, in 1900, Swiss chemist Jacques Brandenberger was enjoying dinner in a restaurant when he noticed that a fellow patron had spilled…