The potential usefulness of 1,1-di-substituted alkenes for making performance polymers has been recognized for some time, but commercialization has been elusive because of the reactive nature of the monomers. Startup company Sirrus Inc. (Loveland, Ohio; www.sirruschemistry.com) has developed technology to…
Evonik Industries AG (Essen, Germany; www.evonik.com) is making an investment in the double-digit-million euro range in a new research center at the Rheinfelden, Germany site. Starting at the beginning of 2016, research into silanes will be carried out in modern…
A less expensive process for producing biodegradeable polyhydroxyalkanoate (PHA) plastics from renewable feedstocks is being scaled up by a factor of six, resulting in a 30,000–60,000-lb/mo pilot facility. The improved PHA process — developed by Meredian Inc. (Bainbridge, Ga.; www.meredianpha.com)…
New bio-based polyimides (PIs) that withstand temperatures up to 390°C — the highest ever reported for a bioplastic — have been developed by Tatsuo Kaneko at the Japan Advanced Institute of Science and Technology (JAIST, Nomi City; www.jaist.ac.jp), in collaboration…
A new thermoset polymer has been discovered by researchers at IBM Research Almaden (San Jose, Calif.; www.research.ibm.com). The new material, polyhexahydrotriazine (PHT), has a very high Young’s Modulus (up to 14 GPa, compared with a Young’s Modulus of 4 GPa…
NEC Corp. (Tokyo, Japan; www.nec.com) has developed a two-stage, heterogeneous synthesis for making a high-functionality bioplastic (70 wt.% plant content) from non-edible plant cellulose. The new bioplastic is said to have excellent thermo-plasticity (275 MFR), heat resistance (140°C glass transition…
While super glassy polymers are initially very porous and ultra-permeable — a property that makes them suitable as gas-separation membranes — they quickly pack into a denser phase becoming less porous and permeable. Now, new materials that prevent such aging…
Oil-water separation A complex formed by combining maleic anhydride copolymers with a cationic fluorosurfactant can separate oil from water when coated on a wire mesh. Researchers at Durham University (U.K.; www.durham.ac.uk) devised a method of preparing the complex in…
Biosynthetic Technologies (Irvine, Calif.; www.biosynthetic.com) has developed a continuous-flow process to convert any animal- or plant-based fatty acids with high oleic-acid content into synthetic esters that can be used in formulations for motor oils and industrial lubricants. These biosynthetic esters…
Since the turn of the new millennium, considerable changes have been taking place in the methanol sector. About ten years ago, methanol plans in the U.S. were being shuttered, while new ones, with much larger capacity — the so-called mega-methanol…