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A new, more comprehensive electronegativity scale

By Gerald Ondrey |

The electronegativity of atoms is one of the most well-known parameters for explaining why chemical reactions occur. Now, Martin Rahm, assistant professor of physical chemistry at Chalmers University of Technology (Gothenburg, Sweden; www.chalmers.se), has redefined the concept with a new, more comprehensive scale. His work, undertaken with colleagues Tao Zeng at Carleton University (Ottawa, Ont., Canada; www.carleton.ca) and Roald Hoffmann at Cornell University (Ithaca, N.Y.; www.cornell.edu), was published in a recent issue of J. Am. Chem. Soc. Numerous electronegativity scales have been developed since the concept was first proposed by Swedish chemist Jöns Jacob Berzelius in the 19th century, but most of these scales only cover parts of the periodic table, typically omitting various heavy or heaviest elements. The new scale covers elements 1 to 96 — the most comprehensive to date. “The new definition is the average binding energy of the outermost and weakest-bound electrons — commonly known as the valence electrons,” explains Rahm. “We derived these values by combining experimental photoionization data with quantum mechanical calculations. By and large, most elements relate to each other in the same way as in earlier…
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