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Plasma-based electrolysis makes ammonia at ambient conditions

Researchers from Case Western Reserve University (CWR; Cleveland, Ohio; www.case.edu) have shown that a hybrid electrolytic system using a gaseous plasma electrode can produce ammonia from water and nitrogen at ambient temperature and pressure — without any catalytic material surface.…

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CO2-to-chemicals effort boosted by electrocatalytic process

The quest to generate chemicals and fuels from exhaust or atmospheric carbon dioxide got a boost from a series of recent studies by researchers at Lawrence Berkeley National Laboratory (LBL; Berkeley, Calif.; www.lbl.gov), in which the scientists proved the viability…

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Artificial enzyme shows multiple selectivity

Professor Kazuaki Ishigreo and colleagues at Nagoya University (Nagoya, Japan; http://en.nagoya-u.ac.jp) have shown that a chiral, supramolecular, U-shaped, boron Lewis acid catalyst (diagram) promotes the unprecedented multi-selective Diels–Alder reaction of propargyl aldehyde with cyclic dienes. The Diels–Alder reaction, which is…

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Industrial-grade salt recovery from zero-liquid-discharge process

A process that increases the water-recovery from reverse osmosis (RO) while producing a salt byproduct is being developed by Hyrec (Urla/Izmir, Turkey; www.hyrec.co). The process, which uses osmotically assisted RO (OARO), could be especially beneficial in coal-to-chemicals (CTC) plants in…

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Chementator Briefs

New PDH capability A new catalyst for propane dehydrogenation (PDH) that does not include precious metals has been developed by KBR Inc. (Houston, Tex.; www.kbr.com). The new catalyst is incorporated into KBR’s new PDH technology, known as K-PRO, which was…

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A low-pressure process to leach metals from laterite ores

Queensland Pacific Metals (Brisbane, Australia), a subsidiary of Pure Minerals (Perth, Australia; www.pureminerals.com.au) will use Direct Nickel Projects’ (Perth, Australia) proprietary technology to process New Caledonian nickel and cobalt ore, following favorable test results. Core Metallurgy (Brisbane, Australia) has assessed…

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A photocatalyst for reducing CO2 without precious metals

The research group of professor Osamu Ishitani at the Tokyo Institute of Technology (Japan; www.titech.ac.jp), in collaboration with the Institute of Advanced Industrial Science and Technology (AIST), has successfully demonstrated highly efficient, selective and durable photocatalytic CO2-reduction systems that only…

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A methane fuel cell that operates at lower temperatures

Existing methane fuel cells typically require high (750–800°C) temperatures to activate methane in a separate methane reformer that creates hydrogen gas. Now researchers at the Georgia Institute of Technology (Georgia Tech; Atlanta; www.gatech.edu) have developed a solid oxide fuel cell…

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A more efficient way to convert CO2 into chemicals via MER

Microbial electrochemical reduction (MER) of CO2 into value-added chemicals is a potential way to curb greenhouse gas (GHG) emissions. MER uses chemolithoautotrophs, which are microbes found in the deep sea, in caves and in hydrothermal vents. These bacteria get their…

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Nano-engineered cellulose prevents scaling

Efforts to find more environmentally friendly anti-scalant approaches have yielded a new form of functionalized nanocellulose that can prevent the nucleation and growth of calcium carbonate, the most common component of industrial scale. Based on the biopolymer cellulose, the anti-scaling…