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A more direct chemical route to ketones

Using a simple, ligand-free palladium catalyst system, researchers at McGill University (Montreal, Que., Canada; www.mcgill.ca) have demonstrated that metal carbonylation — a core chemical reaction for many industrial products — can be used to synthesize ketones directly from hydrocarbons. The…

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A push for ‘green’ steel

Last month, the so-called Hybrit initiative (www.hybritdevelopment.com) was given the go-ahead to build a pilot plant for making fossil-free steel. The announcement follows a pre-feasibility study conducted by Swedish partners SSAB AB (Stockholm; www.ssab.com), LKAB (Luleå; www.lkab.com) and Vattenfall AB…

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‘One-pot’ synthesis of conjugated polyenes

The research group of professor Masafumi Hirando at Tokyo University of Agriculture and Technology (TUAT; Koganei City, Japan; www.tuat.ac.jp) has performed the world’s first one-pot synthesis of conjugated polyenes, which normally require at least seven steps by conventional methods. This…

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Chementator Briefs

Glycolic acid Researchers from the group of professor Miho Yamauchi at the International Institute for Carbon-Neutral Energy Research (I2CNER) of Kyushu University (Fukuoka City, Ito Campus, i2cner.kyushu-u.ac.jp) have fabricated a liquid flow-type electrolyzer that can continuously produce an alcohol from…

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Progress towards aluminum-ion batteries

Compared to conventional lithium-ion batteries, aluminum-ion batteries (AIBs) offer significant advantages, such as non-flammability, and a high capacity of the metallic Al anode. However, due to inadequate cathodic performance, especially capacity, high-rate capability and cycle life, AlBs cannot compete with…

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Biomass fractionation and conversion technology to be scaled up

Plans are underway for a demonstration-scale facility in France that will convert non-food lignocellulosic biomass into raw materials for bio-based chemicals and animal feed products, such as feed for fish farming. The process, developed by Arbiom (Research Triangle Park, N.C.;…

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New process converts refinery offgas into gasoline

A process technology that upgrades offgas from petroleum refineries has been commercialized by Siluria Technologies Inc. (San Francisco, Calif.; www.siluria.com) and Wood (Aberdeen, Scotland; www.woodplc.com). According to Siluria, the new Modus technology’s ability to chemically convert refinery offgases into high-quality…

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Direct conversion of methane into methanol and acetic acid

In a recent paper, published in Nature, the Flytzani-Stephanopoulos group from Tufts University (Medford, Mass.; www.tufts.edu) identified a new method for the direct conversion of methane into methanol or acetic acid under mild conditions using oxygen, carbon monoxide and a…

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Recycled polymers improve the nylon product chain

Although recycled polymers can provide sustainable, low-cost feedstock, their use is challenging in applications that require high-performance characteristics. Vertellus LLC (now Aurorium) has developed additives to improve processors’ ability to incorporate recycled nylons and recycled polyesters into virgin nylon. One…

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Lower-cost sulfur-removal process for syngas goes commercial

An adsorbent-based, sulfur-removal process for synthesis gas (syngas) that lowers capital and operating costs compared to alternative methods of removing sulfur has completed pre-commercial testing and has achieved commercial status. The Warm-gas Desulfurization Process (WDP; diagram) has been under development…