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A sorbent that enhances the water-gas shift reaction

Scientists at the National Energy Technology Laboratory (NETL; Morgantown, W. Va.; www.netl.doe.gov) have demonstrated a process for enhancing the efficiency of the water-gas shift (WGS) reaction. The process revolves around a magnesium hydroxide sorbent material that can remove CO2 from…

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Microporous vanadosilicate efficiently removes cesium from wastewater

The effective removal of Cs+ ions from contaminated groundwater, seawater, and radioactive nuclear waste is crucial for public health and for the operation of nuclear power plants. Although several methods for the removal of Cs+ ions have been developed, there…

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This production process cuts Pt usage in catalytic converters in half

Chemists from the National Institute of Advanced Industrial Science and technology (AIST; Tsukuba City, Japan; www.aist.go.jp) have developed a procedure for making the catalysts used in catalytic converters for treating the exhaust from diesel engines. The process, developed with support…

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Demonstration of methane fermentation to lactic acid

What is said to be the world’s first fermentation pathway from methane to lactic acid has been demonstrated by Calysta, Inc. (Menlo Park, Calif.; www.calysta.com). The fermentation process begins with an organism that feeds off of methane rather than typical…

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Cobalt: a less-expensive and more efficient catalyst than rhodium

The research group of Shigeki Matsunaga, associate professor at the University of Tokyo (Japan; www.f.u-tokyo.ac.jp/~kanai), in collaboration with Ken Sakata at Hoshi University, has developed a new Co-based catalyst system that outperforms the existing rhodium-based catalyst system for the production…

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Platform for reactive monomers enables short cure times for coatings

The potential usefulness of 1,1-di-substituted alkenes for making performance polymers has been recognized for some time, but commercialization has been elusive because of the reactive nature of the monomers. Startup company Sirrus Inc. (Loveland, Ohio; www.sirruschemistry.com) has developed technology to…

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An improved PHA-bioplastic process is scaled up

A less expensive process for producing biodegradeable polyhydroxyalkanoate (PHA) plastics from renewable feedstocks is being scaled up by a factor of six, resulting in a 30,000–60,000-lb/mo pilot facility. The improved PHA process — developed by Meredian Inc. (Bainbridge, Ga.; www.meredianpha.com)…

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This inexpensive bioplastic takes the heat

New bio-based polyimides (PIs) that withstand temperatures up to 390°C — the highest ever reported for a bioplastic — have been developed by Tatsuo Kaneko at the Japan Advanced Institute of Science and Technology (JAIST, Nomi City; www.jaist.ac.jp), in collaboration…

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New polymer is said to be first-ever recyclable thermoset

A new thermoset polymer has been discovered by researchers at IBM Research Almaden (San Jose, Calif.; www.research.ibm.com). The new material, polyhexahydrotriazine (PHT), has a very high Young’s Modulus (up to 14 GPa, compared with a Young’s Modulus of 4 GPa…

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A new route to a cellulose-based bioplastic

NEC Corp. (Tokyo, Japan; www.nec.com) has developed a two-stage, heterogeneous synthesis for making a high-functionality bioplastic (70 wt.% plant content) from non-edible plant cellulose. The new bioplastic is said to have excellent thermo-plasticity (275 MFR), heat resistance (140°C glass transition…