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Electrochemical-redox process expands recycling potential for LFP batteries

Lithium-iron-phosphate (LFP) batteries offer a compelling combination of performance characteristics for stationary energy storage, including improved safety and longevity, when compared to other lithium battery chemistries, such as nickel- and cobalt-based formulations. However, there are limited recycling pathways dedicated to…

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Unique support boosts single-atom indium catalysis of CO2-to-methanol reaction

Synthesis of methanol from carbon dioxide is among the key goals for net-zero-CO2 production of chemicals and fuels. Previous investigation has suggested that indium oxide could serve as an effective catalyst for this reaction, but the structural details of the…

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Gas-fed, solid-state electrolyzer could allow ethylene from waste-derived syngas

Conventional ethylene production via steam cracking of ethane or naphtha leads to the emission of 1 ton of CO2 for every ton of ethylene produced. Given the carbon intensity of the process and the annual volume of ethylene produced (300…

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Thermally switchable solvents allow selective extraction of lithium from brine mixtures

Extracting lithium from currently underutilized brines, such as geothermal and oilfield brines, will be necessary to meet the growing demand for lithium in energy-storage applications in the future. Technical hurdles for extracting lithium from these sources include the relatively low…

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Improved recycling process for PGMs in electrolyzers and fuel cells preserves fluorinated-membrane materials for recovery

Current recycling methods for recovering platinum-group metals (PGMs) from catalyst-coated membranes (CCMs) used in proton-exchange membrane (PEM) electrolyzers and fuel cells incinerate the highly valuable membrane material, requiring the manufacture of new material and the management of hydrogen fluoride offgas…

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Plasmon-assisted electrochemistry allows a greener approach to olefin epoxidation

Olefin epoxidation is an important reaction for making a range of industrial intermediates in processes for epoxy coatings, polyurethanes, polyester textiles, surfactants, specialty chemicals, pharmaceuticals and others. Conventional olefin epoxidation involves organo-peroxides or organo-halogen oxidants, which present safety and environmental…

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Pilot project paves the way for super-efficient ammonia cracking

Ammonia cracking, decomposing ammonia into its constituent nitrogen and hydrogen molecules, is gaining traction as an emerging source for cleaner hydrogen. However, this reaction is very endothermic and requires heat and high temperature. In a proprietary technology developed by Duiker…

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Ionic liquids unlock specialized metal-oxide morphologies

Nanomox (London, U.K.; www.nanomox.net) has invented a synthesis platform for metal oxides where multifunctional ionic liquids enable high selectivity for specialized morphologies. While the technology can be tailored for a large number of metals, the company is currently targeting zinc…

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Nanostructured sorbent and electro-resistive heating lower costs for DAC system

Minimizing cost is the key parameter for the viability of direct-air-capture (DAC) systems that remove carbon dioxide from the atmosphere. The startup company Sustaera Inc. (Research Triangle Park, N.C.; www.sustaera.com) has built a prototype DAC system that it says can…

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Induction-activated catalysis electrifies the production of olefins from plastic waste

A new approach to advanced recycling combines heterogeneous catalysis with electromagnetic induction, enabling the conversion of polyolefin-rich waste streams into versatile materials. Developed by bobine (Strasbourg, France; www.bobine-chemistry.com), this fully electric technology can help decarbonize the production of olefins like…